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Creators/Authors contains: "Valloli, Lakshmy Kannadi"

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  1. Abstract The irradiation of β‐enaminones, generated in situ from cyclic 1,3‐diketones and activated alkenes leads to polyheterocyclic skeletons. The photoproduct chemoselectivity depends on the type of cyclic 1,3‐diketones employed viz., 2‐acetylcyclopentanone and 2‐acetylcyclohexanone. The observed chemoselectivity was rationalized based on the Dieckmann‐Kon rule. 
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  2. Hydrogen bonding mediated control of photochemical reactions is highlighted with an eye towards the development of Brønsted acid mediated photocatalysis. 
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  3. This account highlights the role of restricted bond rotations to influence excited state reactivity of organic molecules. It highlights photochemical reactivity of various organic molecules and the design strategies that could be exploited by chemists to utilize restricted bond rotations to uncover new excited state reactivity and achieve selectivity. 
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    This review highlights the excited state characteristics of imines and processes that govern their photochemical and photophysical properties. This review examines the pathways for deactivation and types of photochemical reactions that originate from excited imines. This review also features recent strategies that are developed to circumvent the fundamental issues that have plagued the development of the aza Paternò–Büchi reaction. 
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